 Herbicide
专利摘要:
The invention relates to agriculture, namely to chemical means for controlling weeds. The purpose of the invention is to increase the stability and herbicidal activity of the agent. Means contains active compound - 公开号:SU1276243A3 申请号:SU813348148 申请日:1981-09-18 公开日:1986-12-07 发明作者:Альбрехт Конрад；Лангелюддеке Петер 申请人:Хехст Аг (Фирма)； IPC主号:
专利说明:
The invention relates to agriculture, namely, chemical ! means of weed control. The purpose of the invention is to increase the stability and herbicidal activity of the composition. In the table. 1 shows compositions containing as an active compound (3-amino-3-carboxy-propyl) - 10 methylphosphinic acid of the formula CHS but / R-CH z CH 2 CH-COOH, "a plural g or its ammonium salt, and provides comparative data on the stability of said compositions at a temperature of about 2 -10, 0 and 20 ° C, from which it follows that the proposed compositions ( 17-24) do not change the physical state after 2 weeks at the indicated temperatures, while in known compositions (1-16) turbidity, precipitation of crystals or phase separation are observed. The proposed products can be used to control mono- and dicotyledonous weeds. The experiments in the greenhouse given in the examples were carried out according to the uniform scheme. The seeds of the test plants are sown in pots. After emergence and the appearance of two leaves in plants, they are sprayed with aqueous solutions (after appropriate dilution of the concentrates) of the proposed, as well as known, control preparations. Preparations are taken in an amount corresponding to a flow rate of 300 l / ha. A few days after the treatment, a visual evaluation of the tests is carried out, the results of which are expressed as% of damage to plants. The given values are average values from the results of three experiments. For a better comparison, the results obtained for various dosages are evaluated graphically using the probit method, and the dosage required to achieve a 95% effect (D 95) is taken as the scale. EXAMPLE 1 Various 33 preparative you experiencing the wild mustard. At the same time, it was found that the drug 19 is clearly superior in the activity of the drug 15, 16, 10-12. Efficiency assessment 14 days after treatment is given in table. 2. Example 2. In a greenhouse on oats, it was found that the proposed preparations 17-24 are also clearly more effective. To achieve the same effect, a significantly smaller number of them is required than the control preparations 1, 8, 13, and 14. Moreover, the most effective Oka drugs are 19-21 (Table 3). Example 3. In a series of field trials in different local conditions, the efficacy of drugs 19 and 1 is compared. It was found that, regardless of local conditions, drug 19 is superior in activity to the control drug. The dosage of the proposed drug required to achieve a 95% effect is significantly lower than that of drug 1. Evaluation of effectiveness 2 weeks after treatment is given in table. 4.
权利要求:
Claims (2) [1] The invention relates to agriculture, namely to chemical means for controlling weeds. The purpose of the invention is to increase the stability and herbicidal activity of the composition. In tab. 1 shows formulations containing (3-amino-3-carboxy-propyl) methylphosphinic acid of the formula CHa O NHr or its ammonium salt as an active compound, and comparative data on the stability of these formulations at a temperature of -10, O and 20 ° C, from which it follows that the proposed formulations (17-24) do not alter the physical state after 2 weeks upon specified temperatures, whereas in the known compositions (1-16) turbidity, precipitation of crystals or phase separation is observed. The proposed agents can be used to control single and dicotyledon weeds. The examples given in the examples in the greenhouse were carried out according to the scheme. Seeds of the test plants were sown in pots. After germination and the appearance of two leaves in plants, they are sprayed with aqueous solutions (after appropriate dilution of the concentrates) of the proposed, as well as known, control preparations. Preparations are taken in an amount corresponding to a flow rate of 300 l / ha. A few days after the treatment, a visual assessment of the tests is performed, the results of which are expressed in% of the damage caused to the plants. The values given are the average of the results of three experiments. For better comparison, the results obtained for different dosages are evaluated graphically using the probit method, with the dosage necessary for achieving a 95% effect (D 95) as a scale. Example 1. Various preparations are tested on mustard field. Previously, it has been established that drug 19 in but exceeds the activity of prepa1;} 2 marta 15, 16, 10-12. Evaluation of the effectiveness of 14 days after treatment are given in table. 2. Example [2] 2. In the greenhouse on oats, it was found that the proposed preparations 17-24 are also clearly more effective. To achieve the same effect, significantly fewer of them are required than the control preparations 1, 8, 13 and 14. At the same time, the most effective way is to record preparations 19-21 (Table 3). Example Z. In a series of field trials in different local conditions, the effectiveness of preparations 19 and 1 is compared. It has been established that, regardless of local conditions, preparation 19 surpasses the control preparation in activity. To achieve the 95% effect, the dosage of the proposed preparation is significantly lower than that of preparation 1. The effectiveness evaluation 2 weeks after the treatment is given in table. 4. Claims of the invention A herbicidal agent containing (3-amino-3-carboxy-propyl) -methylphosphinic acid of the formula CH3 as an active compound. P-CH CH2CH-COOH or its ammonium salt, surfactant, organic solvent and water, characterized in that, in order to increase its stability and activity, the agent contains benzdimethylammonium chloride Cg-Ci8 - alkyl coconut oil or sodium as a surfactant salt of polyglycol ether sulphate С, -C, g-alcohol with 2-6 ethylene oxide groups, and as an organic solvent it contains dimethylformamide, monomethyl ethylene glycol ether or monomethyl propylene glycol ether, with the following the ratio of these components, wt.%: The active compound 10-20 Surfactant 10-30 Organic solvent 15-30 Water Remaining t a (1 p h c 80 thirty 20 104020 LIF 30 104030 Lioxan 20 30 30 104030 104020 104020 30 30 104020 Lioxan 30 104020 ten 5020 D fF20 204020 / (ioxane 20 DM “20 .204020 203020 Lioxan 20 104020 LMF10 103020 20 106020 ten ten LMF. 10 10 6020 105030 (acid) 103030 thirty (acid) 204020 Monome-20 (ammonium distillate salt) lngli- pitch ether .155515 Matil - 15 (lmmonium glycol salt) StvvipPrazrach- Muddy Prozraktl nyytyy Raepeleine fa St.willTransparent crystals: Phase separation - - Phase separation and crystals StabilPrszrach-NutnD Mutiy ny ny Sodium salt of poly-zifira from ethyl acetate sulphate Muddy Muddy StabilCrystal- Muddy Ny ly Muddy Transparent Transparent - Nonklphenolpolyglyko - left ether (10 AeO) Transparent Crystal Ach- Mutny Mutny - Ach- MutshD Transparency Transparent Also Continuation of table Amaranfus hybrdus one nineteen dafura sframonium one nineteen Oryza safiva one nineteen Cynodon dactilon Table 3 : Table 4 2.0 0.6 0.6 0.3 1.2 0.8 Convolvulus arvensis 1 nineteen 1.8 35 60 65 83 1.2
类似技术:
公开号 | 公开日 | 专利标题 SU1276243A3|1986-12-07|Herbicide Hoffmann1962|Chemical seed treatments as herbicidal antidotes US3303090A|1967-02-07|Composition and method for controlling nematodes with organic metal chelates SU667099A3|1979-06-05|Herbicide SU1452459A3|1989-01-15|Method of controlling undesirable vegetation SU628799A3|1978-10-15|Herbicide composition US3268323A|1966-08-23|Method for regulating plant growth SU1181518A3|1985-09-23|Method of fighting weeds US3385689A|1968-05-28|Method of controlling undesirable plant growth SU1209018A3|1986-01-30|Method of controlling weeds DE1955894A1|1970-07-02|Herbicidal and insecticidal agent SU843696A3|1981-06-30|Herbicidic composition US3356724A|1967-12-05|Herbicidal alpha-halo-nu-cyclohexyl-acetamides SU698512A3|1979-11-15|Herbicide SU747398A3|1980-07-23|Herbicide composition SU581837A3|1977-11-25|Herbicide SU579844A3|1977-11-05|Herbicide SU1272966A3|1986-11-23|Method of fighting weeds SU1111673A3|1984-08-30|Method for controlling wild plants SU596149A3|1978-02-28|Herbicide composition SU656464A3|1979-04-05|Herbicide composition US3690865A|1972-09-12|Method of combating unwanted vegetation in sugar beet fields US2701760A|1955-02-08|Herbicidal compositions SU648049A3|1979-02-15|Herbicide US3406179A|1968-10-15|1-|-2-imidazolidone s-|
同族专利:
公开号 | 公开日 EG15124A|1986-12-30| AU7548081A|1982-04-01| CA1171296A|1984-07-24| HU186422B|1985-07-29| DK156610C|1990-02-12| PT73699A|1981-10-01| EP0048436B1|1984-02-15| ZW23481A1|1982-04-14| OA06904A|1983-04-30| DE3162312D1|1984-03-22| DE3035554A1|1982-05-06| MA19272A1|1982-04-01| GR75792B|1984-08-02| CS224627B2|1984-01-16| AU545169B2|1985-07-04| PT73699B|1983-05-11| PL131967B1|1985-01-31| PH18590A|1985-08-12| JPS5782301A|1982-05-22| DK156610B|1989-09-18| ZA816490B|1982-09-29| BR8105969A|1982-06-08| EP0048436A1|1982-03-31| US4400196A|1983-08-23| AR246401A1|1994-08-31| DK416181A|1982-03-21| TR21510A|1984-08-01| MY8600092A|1986-12-31| IL63875A|1986-08-31| PL233083A1|1982-05-10| NZ198398A|1984-12-14| JPH0124765B2|1989-05-15| DD201640A5|1983-08-03|
引用文献:
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申请号 | 申请日 | 专利标题 DE19803035554|DE3035554A1|1980-09-20|1980-09-20|HERBICIDAL AGENTS| 相关专利
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